Dataset: In situ and ISCO data
Deployment: Groves_Creek_2013-2015

S-CAN and geochemical data for Groves Creek

Principal Investigator:

Aron Stubbins (Skidaway Institute of Oceanography, SkIO)

Co-Principal Investigator:

Robert Spencer (Florida State University, FSU)

BCO-DMO Data Manager:

Mathew Biddle (Woods Hole Oceanographic Institution, WHOI BCO-DMO)

Project:

Collaborative Research: Marine priming effect - molecular mechanisms for the biomineralization of terrigenous dissolved organic matter in the ocean (Marine priming effect)

Current State:

Final no updates expected

Version:

Version Date:

2019-02-20

Data URL:

https://www.bco-dmo.org/dataset-deployment/754272/data

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Description

S-CAN and geochemical data for Groves Creek

Methods & Sampling

Dataset acquisition description

In situ instruments deployed at 1 m depth below the surface and as per: Tait, Z. S., M. Thompson, and A. Stubbins (2015) Chemical fouling reduction of a submersible steel spectrophotometer in estuarine environments using a sacrificial zinc anode. Journal of Environmental Quality. doi: 10.2134/jeq2014.11.0484

Samples for laboratory analyses were collected using a refrigerated autosampler (ISCO) which pumped samples from a depth of 1 m below the water surface. Samples were returned to the laboratory and filtered through 0.2 micron Polycap filters within 24 hours of collection.

DOC and TDN using a Shimadzu TOC/TDN analyzer as per automated setup in Stubbins, A., and Dittmar, T. (2012) Low volume quantification of dissolved organic carbon and dissolved nitrogen. Limnology and Oceanography: Methods. doi: 10.4319/lom.2012.10.347.

Lignin via cupric oxide oxidation and GC-MS as per: Spencer, R.G.M., Hernes, P.J., Ruf, R., Baker, A., Dyda, R.Y., Stubbins, A., and Six, J. (2010) Temporal controls on dissolved organic matter and lignin biogeochemistry in a pristine tropical river. Journal of Geophysical Research – Biogeosciences. doi:10.1029/2009JG001180.

Dissolved black carbon by nitric acid oxidation to BPCAs followed by HPLC with spectrophotometric detection as per the non-isotopic method in Wagner, S., Brandes, J., Goranov, A.I., Drake, T. W., Spencer, R. G. W., Stubbins, A. (2017) Online quantification and compound-specific stable isotopic analysis of black carbon in environmental matrices via liquid chromatography-isotope ratio mass spectrometry. Limnology and Oceanography: Methods. doi: 10.1002/lom3.10219.
Nutrients were analyzed using a nutrient analyzer as per: Bittar, T. B., S. A. Berger, L. M. Birsa, T. L. Walters, M. E. Thompson, R. G. M. Spencer, E. L. Mann, A. Stubbins, M. E. Frischer, and J. A. Brandes (2016) Seasonal dynamics of dissolved, particulate and microbial components of a tidal saltmarsh-dominated estuary under contrasting levels of freshwater discharge. Estuarine, Coastal and Shelf Science. doi: 10.1016/j.ecss.2016.08.046.

Data Processing Description

Dataset Processing Description

BCO-DMO Processing Notes:

- combined two data tables into one data table with the same field identifiers.
- added conventional header with dataset name, PI name, version date
- modified parameter names to conform with BCO-DMO naming conventions
- added lat and lon columns
- added date_time column
- added depth column
- removed columns SCAN1,2,3 as the column SCAN_no contains the same information

More information about this dataset deployment

Funding

Award Number	Funding Source
OCE-1356890	NSF Division of Ocean Sciences
OCE-1464392	NSF Division of Ocean Sciences

Instruments

CTD Sea-Bird MicroCAT 37

Supplied Name: microcat

Supplied Description:

In situ temperature and salinity: microcat and YSI sondes

Instrument Type

Generic Name: CTD Sea-Bird MicroCAT 37

Acronym: CTD MicroCAT 37

Community Identifier: http://vocab.nerc.ac.uk/collection/L05/current/350/

Generic Description:

The Sea-Bird MicroCAT CTD unit is a high-accuracy conductivity and temperature recorder based on the Sea-Bird SBE 37 MicroCAT series of products. It can be configured with optional pressure sensor, internal batteries, memory, built-in Inductive Modem, integral Pump, and/or SBE-43 Integrated Dissolved Oxygen sensor. Constructed of titanium and other non-corroding materials for long life with minimal maintenance, the MicroCAT is designed for long duration on moorings.

In a typical mooring, a modem module housed in the buoy communicates with underwater instruments and is interfaced to a computer or data logger via serial port. The computer or data logger is programmed to poll each instrument on the mooring for its data, and send the data to a telemetry transmitter (satellite link, cell phone, RF modem, etc.). The MicroCAT saves data in memory for upload after recovery, providing a data backup if real-time telemetry is interrupted.

Spectrometer

Supplied Name: S-CAN spectrolyzer

Supplied Description:

In situ attenuation: S-CAN spectrolyzer.

Instrument Type

Generic Name: Spectrometer

Community Identifier: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0460/

Generic Description:

A spectrometer is an optical instrument used to measure properties of light over a specific portion of the electromagnetic spectrum.

YSI Sonde 6-Series

Supplied Name: YSI sondes

Supplied Description:

In situ temperature and salinity: microcat and YSI sondes. In situ CDOM fluorescence: YSI sonde

Instrument Type

Generic Name: YSI Sonde 6-Series

Community Identifier: http://vocab.nerc.ac.uk/collection/L22/current/TOOL0737/

Generic Description:

YSI 6-Series water quality sondes and sensors are instruments for environmental monitoring and long-term deployments. YSI datasondes accept multiple water quality sensors (i.e., they are multiparameter sondes). Sondes can measure temperature, conductivity, dissolved oxygen, depth, turbidity, and other water quality parameters. The 6-Series includes several models. More from YSI.

Parameters

Supplied Name	Supplied description	Supplied Units	Standard Name
SCAN_no	spectrophotometer number	unitless	instrument
Excel_Time	value that Microsoft Excel recognizes as a date	unitless	no_bcodmo_term
date_time	date and time formatted as a string following YYYY-MM-DD HH:MM	unitless	date
ISCO_deployment_no	deployment number	unitless	deploy
nm220	light attenuation at 220 nanometers	per meter	beam_cp
nm222_5	light attenuation at 222.5 nanometers	per meter	beam_cp
nm225	light attenuation at 225 nanometers	per meter	beam_cp
nm227_5	light attenuation at 227.5 nanometers	per meter	beam_cp
nm230	light attenuation at 230 nanometers	per meter	beam_cp
nm232_5	light attenuation at 232.5 nanometers	per meter	beam_cp
nm235	light attenuation at 235 nanometers	per meter	beam_cp
nm237_5	light attenuation at 237.5 nanometers	per meter	beam_cp
nm240	light attenuation at 240 nanometers	per meter	beam_cp
nm242_5	light attenuation at 242.5 nanometers	per meter	beam_cp
nm245	light attenuation at 245 nanometers	per meter	beam_cp
nm247_5	light attenuation at 247.5 nanometers	per meter	beam_cp
nm250	light attenuation at 250 nanometers	per meter	beam_cp
nm252_5	light attenuation at 252.5 nanometers	per meter	beam_cp
nm255	light attenuation at 255 nanometers	per meter	beam_cp
nm257_5	light attenuation at 257.5 nanometers	per meter	beam_cp
nm260	light attenuation at 260 nanometers	per meter	beam_cp
nm262_5	light attenuation at 262.5 nanometers	per meter	beam_cp
nm265	light attenuation at 265 nanometers	per meter	beam_cp
nm267_5	light attenuation at 267.5 nanometers	per meter	beam_cp
nm270	light attenuation at 270 nanometers	per meter	beam_cp
nm272_5	light attenuation at 272.5 nanometers	per meter	beam_cp
nm275	light attenuation at 275 nanometers	per meter	beam_cp
nm277_5	light attenuation at 277.5 nanometers	per meter	beam_cp
nm280	light attenuation at 280 nanometers	per meter	beam_cp
nm282_5	light attenuation at 282.5 nanometers	per meter	beam_cp
nm285	light attenuation at 285 nanometers	per meter	beam_cp
nm287_5	light attenuation at 287.5 nanometers	per meter	beam_cp
nm290	light attenuation at 290 nanometers	per meter	beam_cp
nm292_5	light attenuation at 292.5 nanometers	per meter	beam_cp
nm295	light attenuation at 295 nanometers	per meter	beam_cp
nm297_5	light attenuation at 297.5 nanometers	per meter	beam_cp
nm300	light attenuation at 300 nanometers	per meter	beam_cp
nm302_5	light attenuation at 302.5 nanometers	per meter	beam_cp
nm305	light attenuation at 305 nanometers	per meter	beam_cp
nm307_5	light attenuation at 307.5 nanometers	per meter	beam_cp
nm310	light attenuation at 310 nanometers	per meter	beam_cp
nm312_5	light attenuation at 312.5 nanometers	per meter	beam_cp
nm315	light attenuation at 315 nanometers	per meter	beam_cp
nm317_5	light attenuation at 317.5 nanometers	per meter	beam_cp
nm320	light attenuation at 320 nanometers	per meter	beam_cp
nm322_5	light attenuation at 322.5 nanometers	per meter	beam_cp
nm325	light attenuation at 325 nanometers	per meter	beam_cp
nm327_5	light attenuation at 327.5 nanometers	per meter	beam_cp
nm330	light attenuation at 330 nanometers	per meter	beam_cp
nm332_5	light attenuation at 332.5 nanometers	per meter	beam_cp
nm335	light attenuation at 335 nanometers	per meter	beam_cp
nm337_5	light attenuation at 337.5 nanometers	per meter	beam_cp
nm340	light attenuation at 340 nanometers	per meter	beam_cp
nm342_5	light attenuation at 342.5 nanometers	per meter	beam_cp
nm345	light attenuation at 345 nanometers	per meter	beam_cp
nm347_5	light attenuation at 347.5 nanometers	per meter	beam_cp
nm350	light attenuation at 350 nanometers	per meter	beam_cp
nm352_5	light attenuation at 352.5 nanometers	per meter	beam_cp
nm355	light attenuation at 355 nanometers	per meter	beam_cp
nm357_5	light attenuation at 357.5 nanometers	per meter	beam_cp
nm360	light attenuation at 360 nanometers	per meter	beam_cp
nm362_5	light attenuation at 362.5 nanometers	per meter	beam_cp
nm365	light attenuation at 365 nanometers	per meter	beam_cp
nm367_5	light attenuation at 367.5 nanometers	per meter	beam_cp
nm370	light attenuation at 370 nanometers	per meter	beam_cp
nm372_5	light attenuation at 372.5 nanometers	per meter	beam_cp
nm375	light attenuation at 375 nanometers	per meter	beam_cp
nm377_5	light attenuation at 377.5 nanometers	per meter	beam_cp
nm380	light attenuation at 380 nanometers	per meter	beam_cp
nm382_5	light attenuation at 382.5 nanometers	per meter	beam_cp
nm385	light attenuation at 385 nanometers	per meter	beam_cp
nm387_5	light attenuation at 387.5 nanometers	per meter	beam_cp
nm390	light attenuation at 390 nanometers	per meter	beam_cp
nm392_5	light attenuation at 392.5 nanometers	per meter	beam_cp
nm395	light attenuation at 395 nanometers	per meter	beam_cp
nm397_5	light attenuation at 397.5 nanometers	per meter	beam_cp
nm400	light attenuation at 400 nanometers	per meter	beam_cp
nm402_5	light attenuation at 402.5 nanometers	per meter	beam_cp
nm405	light attenuation at 405 nanometers	per meter	beam_cp
nm407_5	light attenuation at 407.5 nanometers	per meter	beam_cp
nm410	light attenuation at 410 nanometers	per meter	beam_cp
nm412_5	light attenuation at 412.5 nanometers	per meter	beam_cp
nm415	light attenuation at 415 nanometers	per meter	beam_cp
nm417_5	light attenuation at 417.5 nanometers	per meter	beam_cp
nm420	light attenuation at 420 nanometers	per meter	beam_cp
nm422_5	light attenuation at 422.5 nanometers	per meter	beam_cp
nm425	light attenuation at 425 nanometers	per meter	beam_cp
nm427_5	light attenuation at 427.5 nanometers	per meter	beam_cp
nm430	light attenuation at 430 nanometers	per meter	beam_cp
nm432_5	light attenuation at 432.5 nanometers	per meter	beam_cp
nm435	light attenuation at 435 nanometers	per meter	beam_cp
nm437_5	light attenuation at 437.5 nanometers	per meter	beam_cp
nm440	light attenuation at 440 nanometers	per meter	beam_cp
nm442_5	light attenuation at 442.5 nanometers	per meter	beam_cp
nm445	light attenuation at 445 nanometers	per meter	beam_cp
nm447_5	light attenuation at 447.5 nanometers	per meter	beam_cp
nm450	light attenuation at 450 nanometers	per meter	beam_cp
nm452_5	light attenuation at 452.5 nanometers	per meter	beam_cp
nm455	light attenuation at 455 nanometers	per meter	beam_cp
nm457_5	light attenuation at 457.5 nanometers	per meter	beam_cp
nm460	light attenuation at 460 nanometers	per meter	beam_cp
nm462_5	light attenuation at 462.5 nanometers	per meter	beam_cp
nm465	light attenuation at 465 nanometers	per meter	beam_cp
nm467_5	light attenuation at 467.5 nanometers	per meter	beam_cp
nm470	light attenuation at 470 nanometers	per meter	beam_cp
nm472_5	light attenuation at 472.5 nanometers	per meter	beam_cp
nm475	light attenuation at 475 nanometers	per meter	beam_cp
nm477_5	light attenuation at 477.5 nanometers	per meter	beam_cp
nm480	light attenuation at 480 nanometers	per meter	beam_cp
nm482_5	light attenuation at 482.5 nanometers	per meter	beam_cp
nm485	light attenuation at 485 nanometers	per meter	beam_cp
nm487_5	light attenuation at 487.5 nanometers	per meter	beam_cp
nm490	light attenuation at 490 nanometers	per meter	beam_cp
nm492_5	light attenuation at 492.5 nanometers	per meter	beam_cp
nm495	light attenuation at 495 nanometers	per meter	beam_cp
nm497_5	light attenuation at 497.5 nanometers	per meter	beam_cp
nm500	light attenuation at 500 nanometers	per meter	beam_cp
nm502_5	light attenuation at 502.5 nanometers	per meter	beam_cp
nm505	light attenuation at 505 nanometers	per meter	beam_cp
nm507_5	light attenuation at 507.5 nanometers	per meter	beam_cp
nm510	light attenuation at 510 nanometers	per meter	beam_cp
nm512_5	light attenuation at 512.5 nanometers	per meter	beam_cp
nm515	light attenuation at 515 nanometers	per meter	beam_cp
nm517_5	light attenuation at 517.5 nanometers	per meter	beam_cp
nm520	light attenuation at 520 nanometers	per meter	beam_cp
nm522_5	light attenuation at 522.5 nanometers	per meter	beam_cp
nm525	light attenuation at 525 nanometers	per meter	beam_cp
nm527_5	light attenuation at 527.5 nanometers	per meter	beam_cp
nm530	light attenuation at 530 nanometers	per meter	beam_cp
nm532_5	light attenuation at 532.5 nanometers	per meter	beam_cp
nm535	light attenuation at 535 nanometers	per meter	beam_cp
nm537_5	light attenuation at 537.5 nanometers	per meter	beam_cp
nm540	light attenuation at 540 nanometers	per meter	beam_cp
nm542_5	light attenuation at 542.5 nanometers	per meter	beam_cp
nm545	light attenuation at 545 nanometers	per meter	beam_cp
nm547_5	light attenuation at 547.5 nanometers	per meter	beam_cp
nm550	light attenuation at 550 nanometers	per meter	beam_cp
nm552_5	light attenuation at 552.5 nanometers	per meter	beam_cp
nm555	light attenuation at 555 nanometers	per meter	beam_cp
nm557_5	light attenuation at 557.5 nanometers	per meter	beam_cp
nm560	light attenuation at 560 nanometers	per meter	beam_cp
nm562_5	light attenuation at 562.5 nanometers	per meter	beam_cp
nm565	light attenuation at 565 nanometers	per meter	beam_cp
nm567_5	light attenuation at 567.5 nanometers	per meter	beam_cp
nm570	light attenuation at 570 nanometers	per meter	beam_cp
nm572_5	light attenuation at 572.5 nanometers	per meter	beam_cp
nm575	light attenuation at 575 nanometers	per meter	beam_cp
nm577_5	light attenuation at 577.5 nanometers	per meter	beam_cp
nm580	light attenuation at 580 nanometers	per meter	beam_cp
nm582_5	light attenuation at 582.5 nanometers	per meter	beam_cp
nm585	light attenuation at 585 nanometers	per meter	beam_cp
nm587_5	light attenuation at 587.5 nanometers	per meter	beam_cp
nm590	light attenuation at 590 nanometers	per meter	beam_cp
nm592_5	light attenuation at 592.5 nanometers	per meter	beam_cp
nm595	light attenuation at 595 nanometers	per meter	beam_cp
nm597_5	light attenuation at 597.5 nanometers	per meter	beam_cp
nm600	light attenuation at 600 nanometers	per meter	beam_cp
nm602_5	light attenuation at 602.5 nanometers	per meter	beam_cp
nm605	light attenuation at 605 nanometers	per meter	beam_cp
nm607_5	light attenuation at 607.5 nanometers	per meter	beam_cp
nm610	light attenuation at 610 nanometers	per meter	beam_cp
nm612_5	light attenuation at 612.5 nanometers	per meter	beam_cp
nm615	light attenuation at 615 nanometers	per meter	beam_cp
nm617_5	light attenuation at 617.5 nanometers	per meter	beam_cp
nm620	light attenuation at 620 nanometers	per meter	beam_cp
nm622_5	light attenuation at 622.5 nanometers	per meter	beam_cp
nm625	light attenuation at 625 nanometers	per meter	beam_cp
nm627_5	light attenuation at 627.5 nanometers	per meter	beam_cp
nm630	light attenuation at 630 nanometers	per meter	beam_cp
nm632_5	light attenuation at 632.5 nanometers	per meter	beam_cp
nm635	light attenuation at 635 nanometers	per meter	beam_cp
nm637_5	light attenuation at 637.5 nanometers	per meter	beam_cp
nm640	light attenuation at 640 nanometers	per meter	beam_cp
nm642_5	light attenuation at 642.5 nanometers	per meter	beam_cp
nm645	light attenuation at 645 nanometers	per meter	beam_cp
nm647_5	light attenuation at 647.5 nanometers	per meter	beam_cp
nm650	light attenuation at 650 nanometers	per meter	beam_cp
nm652_5	light attenuation at 652.5 nanometers	per meter	beam_cp
nm655	light attenuation at 655 nanometers	per meter	beam_cp
nm657_5	light attenuation at 657.5 nanometers	per meter	beam_cp
nm660	light attenuation at 660 nanometers	per meter	beam_cp
nm662_5	light attenuation at 662.5 nanometers	per meter	beam_cp
nm665	light attenuation at 665 nanometers	per meter	beam_cp
nm667_5	light attenuation at 667.5 nanometers	per meter	beam_cp
nm670	light attenuation at 670 nanometers	per meter	beam_cp
nm672_5	light attenuation at 672.5 nanometers	per meter	beam_cp
nm675	light attenuation at 675 nanometers	per meter	beam_cp
nm677_5	light attenuation at 677.5 nanometers	per meter	beam_cp
nm680	light attenuation at 680 nanometers	per meter	beam_cp
nm682_5	light attenuation at 682.5 nanometers	per meter	beam_cp
nm685	light attenuation at 685 nanometers	per meter	beam_cp
nm687_5	light attenuation at 687.5 nanometers	per meter	beam_cp
nm690	light attenuation at 690 nanometers	per meter	beam_cp
nm692_5	light attenuation at 692.5 nanometers	per meter	beam_cp
nm695	light attenuation at 695 nanometers	per meter	beam_cp
nm697_5	light attenuation at 697.5 nanometers	per meter	beam_cp
nm700	light attenuation at 700 nanometers	per meter	beam_cp
nm702_5	light attenuation at 702.5 nanometers	per meter	beam_cp
nm705	light attenuation at 705 nanometers	per meter	beam_cp
nm707_5	light attenuation at 707.5 nanometers	per meter	beam_cp
nm710	light attenuation at 710 nanometers	per meter	beam_cp
nm712_5	light attenuation at 712.5 nanometers	per meter	beam_cp
nm715	light attenuation at 715 nanometers	per meter	beam_cp
nm717_5	light attenuation at 717.5 nanometers	per meter	beam_cp
nm720	light attenuation at 720 nanometers	per meter	beam_cp
nm722_5	light attenuation at 722.5 nanometers	per meter	beam_cp
nm725	light attenuation at 725 nanometers	per meter	beam_cp
nm727_5	light attenuation at 727.5 nanometers	per meter	beam_cp
nm730	light attenuation at 730 nanometers	per meter	beam_cp
DOC_uM	Dissolved Organic Carbon	micro Mole (uM)	DOC
DBC_uM	Dissolved black carbon (DBC)	micro Mole (uM)	no_bcodmo_term
I8_mgper100mgOC_fresh_water	I8 estimate from 8 lignin phenols found in freshwater	units in milligrams lignin per 100 milligrams Organic Carbon	no_bcodmo_term
Lignin_sum8phenol_nM	Dissolved lignin sum8 phenol	nanomole (nM)	no_bcodmo_term
TDN_uM	total dissolved nitrogen (TDN)	micro Mole (uM)	TDN
NO3_NO2_ugNperL	Dissolved nutrients (NO3+NO2)	microgram Nitrogen per Liter (ugN/L)	NO3_NO2
NH4_ugNperL	Dissolved nutrients (NH4)	microgram Nitrogen per Liter (ugN/L)	NH4
PO4_ugPperL	Dissolved nutrients (PO4)	microgram Phosphorus per Liter (ugN/L)	PO4
SiO2_mgperL	Dissolved nutrients (SiO2)	miligram per Liter (mg/L)	no_bcodmo_term
WaterLevel_rel_to_MSL	water level relative to Mean Sea Level	meters	depth
MicroCAT_Salinity	Water salinity	psu	sal
YSI_Salinity	Water salinity	psu	sal
Temp_C_MicroCAT	Water temperature	degrees Celsius	temp
Temp_C_YSI	Water temperature	degrees Celsius	temp
Flour_CDOM	Colored dissolved organic matter (CDOM fluorescence)	unitless	CDOM
Time_Since_Cleaning	Time since cleaning	days	days
DO_mgperL_YSI	Dissolved oxygen	miligrams per liter (mg/L)	O2
B6CA_uM	benzene polycarboxylic acids (B6CA)	microMole (uM)	no_bcodmo_term
B5CA_uM	benzene polycarboxylic acids (B5CA)	microMole (uM)	no_bcodmo_term
B4CA_uM	benzene polycarboxylic acids (B4CA)	microMole (uM)	no_bcodmo_term
BC124_B3CA_uM	benzene polycarboxylic acids (BC124 B3CA)	microMole (uM)	no_bcodmo_term
BC123_B3CA_uM	benzene polycarboxylic acids (BC123 B3CA)	microMole (uM)	no_bcodmo_term
B6CA_B5CA_nM	benzene polycarboxylic acids (B6CA B5CA)	microMole (uM)	no_bcodmo_term
SumS8_ngperL	sum S8	nanogram per Liter (ng/L)	no_bcodmo_term
SumS6_ngperL	sum S6	nanogram per Liter (ng/L)	no_bcodmo_term
I6_mgper100mg_OC_for_marine_water	I6 estimate from 6 lignin phenols found in marine water	milligrams lignin per 100 milligrams Organic Carbon	no_bcodmo_term
Manual_Salinity	Salinity	psu	sal
time_point_type	type of observation (discrete or continuous)	unitless	sample_descrip
lat	latitude north	decimal degrees	lat
lon	longitude east	decimal degrees	lon
depth	depth of samples	meters	depth

Database

Contribute Data

Dataset: In situ and ISCO data
Deployment: Groves_Creek_2013-2015

Dataset acquisition description

Dataset Processing Description

Database

Contribute Data

Dataset: In situ and ISCO dataDeployment: Groves_Creek_2013-2015

Dataset acquisition description

Dataset Processing Description

Dataset: In situ and ISCO data
Deployment: Groves_Creek_2013-2015