Table of Contents

• Coverage
• Dataset Description
  • Methods & Sampling
  • Data Processing Description
• Data Files
• Parameters
• Instruments
• Deployments
• Project Information
• Program Information
• Funding

CTD bottle data from 30-ODF (Ocean Data Facility 12 bottle, 30 liter Niskin rosette) EPZT Transect. TEI columns are incomplete. Refer to separate TEI datasets from GEOTRACES EPZT for those values.

ODF CTD BOTTLE 20141030ODF

Note: 'FLAG_W' columns = WHP (WOCE Hydrographic Program) quality flags.

From the TN303 cruise report:
Two types of rosette/SBE9plus CTD casts (ODF/30L-Niskin and GT-C/12L-GoFlo) were made at 36 station locations during U.S. GEOTRACES EPZT. Deep ODF/30L-Niskin casts included a device suspended 20 meters below the rosette, designed either to take a core sample or pick up particulates from the sea floor.

ODF/30L-Niskin Rosette/CTD casts were performed with a package consisting of a 12-bottle rosette frame (SIO/STS), a 12- or 24-place carousel (SBE32) and 12 ea. 30L General Oceanics Niskin-style bottles with an absolute volume of 30L each. 

 A 12-place carousel was used on station 1, but had repeated trip-confirmation failures during stations 2 and 3. It was replaced with an older 24-place carousel mid-station 3, which resolved the trip-confirmation issues. Prior to station 4, the carousel head was replaced by one with titanium instead of stainless steel latches in order to resolve mechanical tripping
issues. This "hybrid" carousel was used successfully for the remainder of the cruise.

Underwater electronic components consisted of a Sea-Bird Electronics CTD (SBE9plus) with dual pumps (SBE5), dual temperature (SBE3plus), reference temperature (SBE35RT), dual conductivity (SBE4C), dissolved oxygen (SBE43), transmissometer (WET Labs C-Star), fluorometer (Seapoint SCF), Oxidation Reduction Potention (ORP) sensor (NOAA), turbidity meter (Seapoint STM11) and altimeter (Simrad 807). A second dissolved oxygen + oxygen temperature sensor (JFE Advantech RINKO-III) was incorporated into the data stream for future sensor evaluation; it was not processed for this cruise. Additionally, an SBE19plus CTD was mounted on the rosette during deep ODF casts for full and super stations beginning with station 25, since it could no longer be deployed on deep McLane pump casts after their wire was damaged.

Shipboard CTD data processing was performed automatically at the end of each deployment using SIO/STS CTD processing software v.5.1.6-1. Raw GT-C CTD data and bottle trip files, acquired by SBE Seasave V 7.17a on a Windows XP workstation, were also imported into the Linux processing system, providing a backup of the raw data.

Pre-cruise laboratory calibrations were applied, then CTD data were processed into a 0.5-second time series, bottle trips were extracted, and a 1-decibar down-cast pressure series of the data was created. The pressure-series data were used by the web service for interactive plots, sections and CTD data distribution. Time-series data, and eventually basic up-cast pressure-series data, were also available for distribution through the website.

SIO/ODF CTD data were examined at the completion of each deployment for clean, corrected sensor response and any calibration shifts. As bottle salinity and oxygen results became available, they were used to refine shipboard conductivity and oxygen sensor calibrations.

Processing notes from README provided by ODF:
The CTD depths in the shipboard version (20 Dec 2013) of the data - bottle data in particular - were originally calculated incorrectly due to two software errors.  A small error in the gravity calculation affected both bottle and CTD data. In addition, the bottle file CTDDEPTH calculation was inadvertently using a combination of latitude and longitude, vs just latitude, as input to the gravity component of the depth equation, causing up to a 20m error in some of the casts.

Two different depth calculations were subsequently added into these data files: the original, integrated Saunders-Mantyla integrated depth calculations (SMDEPTH), with the gravity error corrected; and the non-integrated Fofonoff-Millard depth calculations (FMDEPTH), same as those used by SBE. The Fofonoff-Millard depths are used for the primary CTDDEPTH column in both bottle data files.

ODF reports that the CTDDEPTH column agreed best with depths identified from CTD bottle trips recorded during GEOTRACES CTD acquisition. The depth values in CTDDEPTH column are from the Saunders & Fofonoff 1976 calculation of depth from pressure. This is the same default calculation of depth used by SeaBird (SBE) software. GEOTRACES CTD data acquisition uses SBE software. It follows that it would be preferable and consistent for GEOTRACES and ODF to use the values in the CTDDEPTH column.

The ODF CTD data files are fully processed for PTCO. Lab calibrations were applied, except for CTDO2; then shipboard corrections were determined and applied to all 4 parameters using ODF software. The PI for ODF CTD and bottle data is:
Dr. James H. Swift (UCSD/SIO) (jswift@ucsd.edu.)
Questions should (also) be directed to: Susan M. Becker, ODF Supervisor (sbecker@ucsd.edu) and Mary C. Johnson, data processor (mcj@ucsd.edu)

Processing notes from README_1410.txt:
Separate columns of S-M and F-M depths ("SMDEPTH" and "FMDEPTH") are included in bottle and CTD files. In addition, "ODF_CTDPRS" is an added column in the bottle files. This may differ from the main CTDPRS in the bottle file only for EPZT GT-C casts, where Seasave-processed CTD trip data were used.

Note: 'FLAG_W' columns = WHP (WOCE Hydrographic Program) quality flags. ODF used the WHP quality coding schema, but also included two non-standard quality codes in the GT-C bottle file:
- QUALITY CODE 'A' WAS USED FOR DATA VALUES SUBMITTED AS 'ABOVE DETECTION LIMITS'
- QUALITY CODE 'B' WAS USED FOR DATA VALUES SUBMITTED AS 'BELOW DETECTION LIMITS'
This was at the request of two different PIs.

From the NSF Award Abstract
The mission of the International GEOTRACES Program (https://www.geotraces.org/), of which the U.S. chemical oceanography research community is a founding member, is "to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions" (GEOTRACES Science Plan, 2006). In the United States, ocean chemists are currently in the process of organizing a zonal transect in the eastern tropical South Pacific (ETSP) from Peru to Tahiti as the second cruise of the U.S.GEOTRACES Program. This Pacific section includes a large area characterized by high rates of primary production and particle export in the eastern boundary associated with the Peru Upwelling, a large oxygen minimum zone that is a major global sink for fixed nitrogen, and a large hydrothermal plume arising from the East Pacific Rise. This particular section was selected as a result of open planning workshops in 2007 and 2008, with a final recommendation made by the U.S.GEOTRACES Steering Committee in 2009. It is the first part of a two-stage plan that will include a meridional section of the Pacific from Tahiti to Alaska as a subsequent expedition.

This award provides funding for management of the U.S.GEOTRACES Pacific campaign to a team of scientists from the University of Southern California, Old Dominion University, and the Woods Hole Oceanographic Institution. The three co-leaders will provide mission leadership, essential support services, and management structure for acquiring the trace elements and isotopes samples listed as core parameters in the International GEOTRACES Science Plan, plus hydrographic and nutrient data needed by participating investigators. With this support from NSF, the management team will (1) plan and coordinate the 52-day Pacific research cruise described above; (2) obtain representative samples for a wide variety of trace metals of interest using conventional CTD/rosette and GEOTRACES Sampling Systems; (3) acquire conventional JGOFS/WOCE-quality hydrographic data (CTD, transmissometer, fluorometer, oxygen sensor, etc) along with discrete samples for salinity, dissolved oxygen (to 1 uM detection limits), plant pigments, redox tracers such as ammonium and nitrite, and dissolved nutrients at micro- and nanomolar levels; (4) ensure that proper QA/QC protocols are followed and reported, as well as fulfilling all GEOTRACES Intercalibration protocols; (5) prepare and deliver all hydrographic-type data to the GEOTRACES Data Center (and US data centers); and (6) coordinate cruise communications between all participating investigators, including preparation of a hydrographic report/publication.

Broader Impacts: The project is part of an international collaborative program that has forged strong partnerships in the intercalibration and implementation phases that are unprecedented in chemical oceanography. The science product of these collective missions will enhance our ability to understand how to interpret the chemical composition of the ocean, and interpret how climate change will affect ocean chemistry. Partnerships include contributions to the infrastructure of developing nations with overlapping interests in the study area, in this case Peru. There is a strong educational component to the program, with many Ph.D. students carrying out thesis research within the program.

Figure 1. The 2013 GEOTRACES EPZT Cruise Track. [click on the image to view a larger version]

GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.

GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;

* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and

* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.

GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.

Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.