Water column Th-234 activity determined using a 4-L technique from samples collected on R/V Melville cruise MV1008 in the Costa Rica Dome in 2010 (CRD FLUZiE project)

Website: https://www.bco-dmo.org/dataset/516062
Data Type: Cruise Results
Version: 1
Version Date: 2014-05-28

Project
» Costa Rica Dome FLUx and Zinc Experiments (CRD FLUZiE)

Programs
» Integrated Marine Biogeochemistry and Ecosystem Research -US (IMBER-US)
» Ocean Carbon and Biogeochemistry (OCB)
ContributorsAffiliationRole
Landry, Michael R.University of California-San Diego Scripps (UCSD-SIO)Principal Investigator
Stukel, Michael R.University of Maryland Center for Environmental Science (UMCES/HPL)Contact
Rauch, ShannonWoods Hole Oceanographic Institution (WHOI BCO-DMO)BCO-DMO Data Manager

Abstract
Water column Thorium-234 and Uranium-238 measured on the MV1008 cruise in the Costa Rica Dome (CRD) region of the Eastern Tropical Pacific Ocean.


Coverage

Spatial Extent: N:10.33 E:-86.76 S:8.37 W:-92.92
Temporal Extent: 2010-06-27 - 2010-07-23

Dataset Description

Water column Thorium-234 and Uranium-238 measured on the MV1008 cruise in the Costa Rica Dome (CRD) region of the Eastern Tropical Pacific Ocean.


Methods & Sampling

4-L samples for analysis of water column 234Th concentrations were typically taken at 12 depths spanning the upper 150 m on two casts per experimental cycle. On two cycles in the core of the CRD, an additional set of 8 samples was taken to assess 234Th deficiency down to 500-m depth. Samples were analyzed by standard small volume procedures (Benitez-Nelson et al. 2001, Buesseler et al. 2001, Pike et al. 2005). Immediately after collection, samples were acidified to a pH < 2 with concentrated HNO3, spiked with 1 mL 230Th tracer (0.17 Bq mL-1), shaken vigorously, and allowed to equilibrate for 4-9 hours. Samples were then basified to a pH of 8-9 with NH4OH. 100 uL each of KMnO4 (7.5 g L-1) and MnCl2 (33 g L-1) were added and samples were shaken then allowed to sit for >8 hours as Th co-precipitated with manganese oxide. Samples were then filtered at high pressure onto a quartz microfiber (QMA) filter, dried in a drying oven, and mounted into RISO sample holders for beta counting.

Samples were beta counted at the University of South Carolina on a RISO low-level beta multi-counter within two months of the collection date. After an additional 8 months, samples were recounted to determine background beta emissions. Detector efficiency was calibrated using four samples taken from 2000-m depth (in water columns exceeding 3000-m depth), which were assumed to be at equilibrium with respect to 234Th and 238U. After background counts yield analyses were conducted as follows. Manganese oxide precipitate was dissolved from filters in 10 mL 8M HNO3/10% H2O2. 1 mL of 229Th (1.66 Bq g-1) tracer was then added gravimetrically, and the sample was sonicated for 20 minutes and allowed to sit for >6 hours. An aliquot of this solution was then filtered through a 0.1-mm syringe filter and diluted with 2.2M HNO3/1%HF for mass spec analysis of the 229:230Th tracer ratio at the Woods Hole Oceanographic Institution Analytical Facility.


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Data Files

File
Th234_activity.csv
(Comma Separated Values (.csv), 9.62 KB)
MD5:c1f42b632a110d357f6ccab5fd358a4f
Primary data file for dataset ID 516062

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Parameters

ParameterDescriptionUnits
event

Number referring to the particular deployment activity (event) on the FluZiE cruise.

integer
cast

CTD Cast number from the FluZiE cruise.

integer
niskin

Niskin bottle that the sample was taken from.

integer
cycle

Refers to the 4-day Lagrangian experiment during which the sample was taken.

integer
sample

Refers to a specific 234Th measurement.

unitless
lat

Latitude (in degrees North) where the sample was collected.

decimal degrees
lon

Longitude (in degrees East) where the sample was collected.

decimal degrees
depth

Depth (in meters) that the sample was taken from as determined by CTD.

meters
sal

Salinity determined by CTD.

practical salinity units (PSU)
density

Density determined by CTD.

kilograms per cubic meter (kg m-3)
U238_activity

The activity of Uranium-238 (238U) estimated from salinity using the equation of Owens et al. (2011).

decays per minute per liter (dpm L-1)
Th234_activity

The activity of Thorium-234 (234Th).

decays per minute per liter (dpm L-1)
uncertainty

The uncertainty in 234Th activity determined by propagating our measurement uncertainty.

decays per minute per liter (dpm L-1)
ISO_DateTime_UTC

Date and time (UTC) of CTD cast from which the water was drawn formatted to ISO 8601 standard. format: YYYY-mm-ddTHH:MM:SS.xx

unitless


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Instruments

Dataset-specific Instrument Name
Mass Spec
Generic Instrument Name
Mass Spectrometer
Dataset-specific Description
Mass spec analysis of the 229:230Th tracer ratio took place at the Woods Hole Oceanographic Institution Analytical Facility.
Generic Instrument Description
General term for instruments used to measure the mass-to-charge ratio of ions; generally used to find the composition of a sample by generating a mass spectrum representing the masses of sample components.

Dataset-specific Instrument Name
RISO low-level beta multi-counter
Generic Instrument Name
Riso Laboratory Anti-coincidence Beta Counters
Dataset-specific Description
Samples were beta counted at the University of South Carolina on a RISO low-level beta multi-counter within two months of the collection date.
Generic Instrument Description
Low-level beta detectors manufactured by Riso (now Nutech) in Denmark. These instruments accept samples that can be mounted on a 25mm filter holder. These detectors have very low backgrounds, 0.17 counts per minute, and can have counting efficiencies as high as 55%. Typically used in laboratory analyses. Designed to measure low levels of beta particle emission. The systems work on the principle of anticoincidence.


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Deployments

MV1008

Website
Platform
R/V Melville
Report
Start Date
2010-06-22
End Date
2010-07-25
Description
Research on the cruise was aimed at acquiring a better understanding of plankton dynamics, carbon and nutrient fluxes, and potential trace element limitation in the Costa Rica Dome region of the eastern tropical Pacific. The specific science objectives were: 1) to assess grazing and trace metal/nutrient controls on primary production and phytoplankton standing stocks; 2) to quantify carbon and elemental fluxes and export rates from the euphotic zone; and 3) to measure microbial population, processes, stable isotope abundances associated with the OMZ and nitrite maxima. Operations included: 4-day sediment trap deployments, daily process experiments conducted on satellite-tracked drifters, CTD and trace-metal rosette sampling, shipboard grow-out experiments, net sampling for zooplankton biomass and grazing assessments, and MOCNESS stratified tows to 1000 m. BCO-DMO Note: March 2013 (CLC): The original CTD profile data (85 casts) have been submitted by R2R to NODC.  Jim Moffett (USC) was a participant on this cruise and is interested in getting a copy of the full set of CTD cast data (deep and shallow casts). He plans to contact SIO ODF group or Mike Landry (Chief Scientist). Original cruise data are available from the NSF R2R data catalog.


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Project Information

Costa Rica Dome FLUx and Zinc Experiments (CRD FLUZiE)

Coverage: Costa Rica Dome, Eastern Tropical Pacific Ocean


Research was aimed at improved understanding of plankton dynamics, carbon and nutrient fluxes, and potential trace element limitation in the Costa Rica Dome region of the eastern tropical Pacific. The specific science objectives of the 2010 R/V Melville cruise (MV1008) were:
1) to assess grazing and trace metal/nutrient controls on primary production and phytoplankton standing stocks;
2) to quantify carbon and elemental fluxes and export rates from the euphotic zone; and
3) to measure microbial population, processes, stable isotope abundances associated with the OMZ and nitrite maxima.

Additional information about MV1008 can be found in the cruise report (PDF).

NOTE: The original proposal and award abstract are not relevant. The project was originally funded by NSF as experimental tests of phytoplankton controls in the Arabian Sea. Piracy concerns in the region led to the cancellation of the research cruise in 2009, and a Change of Scope request was approved to focus the project on related issues in the Costa Rica Dome (CRD).

Though this project is not formally affiliated with any large program, it aligns with IMBER's emphasis on community ecology and biogeochemistry, and the OCB focus on carbon-based measurements of production, grazing and export processes.



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Program Information

Integrated Marine Biogeochemistry and Ecosystem Research -US (IMBER-US)


Coverage: global


The BCO-DMO database includes data from IMBER endorsed projects lead by US funded investigators. There is no dedicated US IMBER project or data management office. Those functions are provided by US-OCB and BCO-DMO respectively.

The information in this program description pertains to the Internationally coordinated IMBER research program. The projects contributing data to the BCO-DMO database are those funded by US NSF only. The full IMBER data catalog is hosted at the Global Change Master Directory (GCMD). 

IMBER Data Portal: The IMBER project has chosen to create a metadata portal hosted by the NASA's Global Change Master Directory (GCMD). The GCMD IMBER data catalog provides an overview of all IMBER endorsed and related projects and links to datasets, and can be found at URL http://gcmd.nasa.gov/portals/imber/.

IMBER research will seek to identify the mechanisms by which marine life influences marine biogeochemical cycles, and how these, in turn, influence marine ecosystems. Central to the IMBER goal is the development of a predictive understanding of how marine biogeochemical cycles and ecosystems respond to complex forcings, such as large-scale climatic variations, changing physical dynamics, carbon cycle chemistry and nutrient fluxes, and the impacts of marine harvesting. Changes in marine biogeochemical cycles and ecosystems due to global change will also have consequences for the broader Earth System. An even greater challenge will be drawing together the natural and social science communities to study some of the key impacts and feedbacks between the marine and human systems.

To address the IMBER goal, four scientific themes, each including several issues, have been identified for the IMBER project: Theme 1 - Interactions between Biogeochemical Cycles and Marine Food Webs; Theme 2 - Sensitivity to Global Change: How will key marine biogeochemical cycles, ecosystems and their interactions, respond to global change?; Theme 3 - Feedback to the Earth System: What are the roles of the ocean biogeochemistry and ecosystems in regulating climate?; and Theme 4 - Responses of Society: What are the relationships between marine biogeochemical cycles, ecosystems, and the human system?


Ocean Carbon and Biogeochemistry (OCB)


Coverage: Global


The Ocean Carbon and Biogeochemistry (OCB) program focuses on the ocean's role as a component of the global Earth system, bringing together research in geochemistry, ocean physics, and ecology that inform on and advance our understanding of ocean biogeochemistry. The overall program goals are to promote, plan, and coordinate collaborative, multidisciplinary research opportunities within the U.S. research community and with international partners. Important OCB-related activities currently include: the Ocean Carbon and Climate Change (OCCC) and the North American Carbon Program (NACP); U.S. contributions to IMBER, SOLAS, CARBOOCEAN; and numerous U.S. single-investigator and medium-size research projects funded by U.S. federal agencies including NASA, NOAA, and NSF.

The scientific mission of OCB is to study the evolving role of the ocean in the global carbon cycle, in the face of environmental variability and change through studies of marine biogeochemical cycles and associated ecosystems.

The overarching OCB science themes include improved understanding and prediction of: 1) oceanic uptake and release of atmospheric CO2 and other greenhouse gases and 2) environmental sensitivities of biogeochemical cycles, marine ecosystems, and interactions between the two.

The OCB Research Priorities (updated January 2012) include: ocean acidification; terrestrial/coastal carbon fluxes and exchanges; climate sensitivities of and change in ecosystem structure and associated impacts on biogeochemical cycles; mesopelagic ecological and biogeochemical interactions; benthic-pelagic feedbacks on biogeochemical cycles; ocean carbon uptake and storage; and expanding low-oxygen conditions in the coastal and open oceans.



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Funding

Funding SourceAward
NSF Division of Ocean Sciences (NSF OCE)

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