Table of Contents

• Dataset Description
  • Methods & Sampling
  • Data Processing Description
• Data Files
• Parameters
• Instruments
• Deployments
• Project Information
• Program Information
• Funding

Concentrations of dissolved manganese in water-column samples from major stations that were occupied during the U.S. GEOTRACES Eastern Pacific Zonal Transect cruise (GEOTRACES cruise GP16). Note: These supersede the preliminary results of shipboard analyses listed as “Mn_DISS” in the BCO-DMO file "CTD – GT-C Bottle". 

Water-column samples for trace metal analysis were collected in modified 12 L Teflon-lined GO-FLO samplers (General Oceanics Inc.), deployed on the U.S. GEOTRACES clean CTD rosette system with a total of 24 samplers). At each station, the bottles were deployed open and tripped on ascent at 3 m/min. On deck, the bottles were kept in a trace metal clean sampling van over-pressurized with HEPA-filtered air, except immediately prior to and following deployments, in which cases they were covered on both ends with shower caps to avoid deck contamination. All samples were filtered as soon as possible after recovery by GEOTRACES sampling personnel using 0.2 um Supor Acropak filter cartridge (Pall Corp.) inside the U.S. GEOTRACES clean-air laboratory van. Near-surface samples (from ~2 m depth) were collected while underway on approach to or departure from each station using the Bruland-Smith "Geofish" sampling system, which was towed outside of the ship’s wake. Seawater from the Geofish was pumped into a clean-air laboratory van, where it was filtered through 0.2 um Supor Acropak filter cartridges. After sample collection, the exteriors of the bottles were rinsed once with De-ionized water and dried under a laminar flow hood. Samples were acidified within 24 hours with 0.2 mLs of 6N to a pH of ~1.8. Samples were analyzed at sea within 1 month of collection.

Dissolved Mn was determined at sea by flow injection analysis with in-line pre-concentration on resin-immobilized 8-hydroxyquinoline and colorimetric detection. Daily precision of analysis was +/- 0.01 nM or 3.8%, whichever is larger, based on the reproducibility of analytical and internal standards. A conservative estimate of the limit of detection is 0.03 nM based on 3 times the daily precision of analysis, which is consistent with previous work. Two internal reference standards were run over the 57 days of the cruise, with DMn concentrations of 0.42 +/- 0.036 nM (+/- 8.4%; n = 102) and 0.31 +/- 0.041 nM (+/- 13%, n = 69), respectively. The SAFe reference samples were analyzed simultaneously during sample analysis with the following results: for SAFe S, 0.85 +/- 0.026 nM (n = 27; consensus value = 0.79 +/- 0.06 nM); for SAFe D2, 0.40 +/- 0.028 nM (n = 22; consensus value = 0.35 +/- 0.05); and for SAFe D1, 0.36 +/- 0.026 nM (n = 31; no consensus value). 

Intercalibration information:
In addition to the reference standards reported above, we conducted an intercomparisson with three other labs University of California Santa Cruz, University of Southern Mississippi, University of Miami. The stations considered were 1, 17 and 36 (for the UM  group we compare only stations 17 and 36.)

This intercalibration was accepted by the International GEOTRACES Standards and Intercalbration Committee.

Related References:
Resing, J. A. & Mottl, M. J. Determination of manganese in seawater using flow injection analysis with on-line preconcentration and spectrophotometric detection. Anal. Chem. 64, 2682–2687 (1992).

Data Processing:
Concentrations were calculated using regressions fits to daily calibration curves obtained by additions of manganese standard solutions to low-manganese seawater.

BCO-DMO Processing:
- modified parameter names to conform with BCO-DMO and GEOTRACES naming conventions;
- replaced missing data with 'nd' (no data);
- joined to BCO-DMO EPZT master events file;
- separated TEI data into different columns for BOTTLE and FISH samples, in accordance with GEOTRACES naming conventions;
- 30 June 2017: removed duplicate row for GEOTRACES sample #8332.

Additional GEOTRACES Processing:
As was done for the GEOTRACES-NAT data, BCO-DMO added standard US GEOTRACES information, such as the US GEOTRACES event number, to each submitted dataset lacking this information. To accomplish this, BCO-DMO compiled a 'master' dataset composed of the following parameters:

cruise_id, EXPOCODE,SECT_ID, STNNBR, CASTNO, GEOTRC_EVENTNO, GEOTRC_SAMPNO, GEOTRC_INSTR, SAMPNO, GF_NO, BTLNBR, BTLNBR_FLAG_W, DATE_START_EVENT, TIME_START_EVENT, ISO_DATETIME_UTC_START_EVENT, EVENT_LAT, EVENT_LON, DEPTH_MIN, DEPTH_MAX,  BTL_DATE, BTL_TIME, BTL_ISO_DATETIME_UTC, BTL_LAT, BTL_LON, ODF_CTDPRS, SMDEPTH, FMDEPTH, BTMDEPTH, CTDPRS, CTDDEPTH.

This added information will facilitate subsequent analysis and inter comparison of the datasets.

Bottle parameters in the master file were taken from the GT-C_Bottle and ODF_Bottle datasets. Non-bottle parameters, including those from GeoFish tows, Aerosol sampling, and McLane Pumps, were taken from the TN303 Event Log (version 30 Oct 2014). Where applicable, pump information was taken from the PUMP_Nuts_Sals dataset.

A standardized BCO-DMO method (called "join") was then used to merge the missing parameters to each US GEOTRACES dataset, most often by matching on sample_GEOTRC or on some unique combination of other parameters.

If the master parameters were included in the original data file and the values did not differ from the master file, the original data columns were retained and the names of the parameters were changed from the PI-submitted names to the standardized master names. If there were differences between the PI-supplied parameter values and those in the master file, both columns were retained. If the original data submission included all of the master parameters, no additional columns were added, but parameter names were modified to match the naming conventions of the master file.

See the dataset parameters documentation for a description of which parameters were supplied by the PI and which were added via the join method.

From the NSF Award Abstract
The mission of the International GEOTRACES Program (https://www.geotraces.org/), of which the U.S. chemical oceanography research community is a founding member, is "to identify processes and quantify fluxes that control the distributions of key trace elements and isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions" (GEOTRACES Science Plan, 2006). In the United States, ocean chemists are currently in the process of organizing a zonal transect in the eastern tropical South Pacific (ETSP) from Peru to Tahiti as the second cruise of the U.S.GEOTRACES Program. This Pacific section includes a large area characterized by high rates of primary production and particle export in the eastern boundary associated with the Peru Upwelling, a large oxygen minimum zone that is a major global sink for fixed nitrogen, and a large hydrothermal plume arising from the East Pacific Rise. This particular section was selected as a result of open planning workshops in 2007 and 2008, with a final recommendation made by the U.S.GEOTRACES Steering Committee in 2009. It is the first part of a two-stage plan that will include a meridional section of the Pacific from Tahiti to Alaska as a subsequent expedition.

This award provides funding for management of the U.S.GEOTRACES Pacific campaign to a team of scientists from the University of Southern California, Old Dominion University, and the Woods Hole Oceanographic Institution. The three co-leaders will provide mission leadership, essential support services, and management structure for acquiring the trace elements and isotopes samples listed as core parameters in the International GEOTRACES Science Plan, plus hydrographic and nutrient data needed by participating investigators. With this support from NSF, the management team will (1) plan and coordinate the 52-day Pacific research cruise described above; (2) obtain representative samples for a wide variety of trace metals of interest using conventional CTD/rosette and GEOTRACES Sampling Systems; (3) acquire conventional JGOFS/WOCE-quality hydrographic data (CTD, transmissometer, fluorometer, oxygen sensor, etc) along with discrete samples for salinity, dissolved oxygen (to 1 uM detection limits), plant pigments, redox tracers such as ammonium and nitrite, and dissolved nutrients at micro- and nanomolar levels; (4) ensure that proper QA/QC protocols are followed and reported, as well as fulfilling all GEOTRACES Intercalibration protocols; (5) prepare and deliver all hydrographic-type data to the GEOTRACES Data Center (and US data centers); and (6) coordinate cruise communications between all participating investigators, including preparation of a hydrographic report/publication.

Broader Impacts: The project is part of an international collaborative program that has forged strong partnerships in the intercalibration and implementation phases that are unprecedented in chemical oceanography. The science product of these collective missions will enhance our ability to understand how to interpret the chemical composition of the ocean, and interpret how climate change will affect ocean chemistry. Partnerships include contributions to the infrastructure of developing nations with overlapping interests in the study area, in this case Peru. There is a strong educational component to the program, with many Ph.D. students carrying out thesis research within the program.

Figure 1. The 2013 GEOTRACES EPZT Cruise Track. [click on the image to view a larger version]

Description from NSF award abstract:
The 2013 GEOTRACES Eastern Pacific Zonal transect cruise will transit from the highly productive coastal upwelling region off Peru to the stratified oligotrophic waters of the South Pacific subtropical gyre on its way to Tahiti. A range of subsurface oxygen depleted water and sedimentary inputs from the Peru margin will be encountered, as well as hydrothermal vents at 15°S on the East Pacific Rise (EPR). Scientists from the University of Washington and Old Dominion University plan to analyze seawater samples for dissolved and total-dissolvable aluminum (Al), manganese (Mn), and iron (Fe) in water column samples. The dissolved Al, Mn, and Fe in samples from the upper water column (<1000 m depth) will be analyzed onboard to ensure samples being collected are uncontaminated, as well as samples from west of the EPR at hydrothermal plume depths. The shipboard analyses will be augmented by shore-based analyses of water column samples from all depths, as well as analyses of total-dissolvable Al, Mn, and Fe, which will complement the direct analyses of particulate metals undertaken by other GEOTRACES investigators. Results will be used to test the following hypotheses concerning the sources and cycling of Al, Mn and Fe in the ocean: (1) when Aeolian inputs are relatively constant, dissolved Al concentrations in surface waters vary as a function of biological production; (2) concentration maxima of dissolved Al, Mn, and Fe in subsurface waters of the Eastern Pacific oxygen minimum zone are the result of lateral transport from the continental margin by means of resuspension and remobilization; and (3) values about ambient levels with conservative behavior will be encountered in the neutrally buoyant plume about the East Pacific Rise ridge crest for dissolved Fe and Al.

As regards broader impacts, results from the study would be disseminated to the public via lectures, the internet, and press releases. One graduate and one undergraduate student from the University of Washington would be supported and trained as part of this project.

GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.

GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;

* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and

* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.

GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.

Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.