Dataset: Comparison of Membrane Inlet Mass Spectrometry (MIMS) to Isotope Ratio Mass Spectrometer (IRMS)

ValidatedFinal no updates expectedDOI: 10.1575/1912/bco-dmo.778065.1Version 1 (2019-10-02)Dataset Type:experimental

Principal Investigator: Julie Granger (University of Connecticut)

Co-Principal Investigator: Annie Bourbonnais (University of Massachusetts Dartmouth)

Co-Principal Investigator: Samuel Wilson (University of Hawai'i)

BCO-DMO Data Manager: Mathew Biddle (Woods Hole Oceanographic Institution)


Project: EAGER: Collaborative Research: Detection limit in marine nitrogen fixation measurements - Constraints of rates from the mesopelagic ocean (EAGER NitFix)


Abstract

In order to ensure that 15N2 atom% effectuated by Membrane Inlet Mass Spectrometry, we tested whether the mass-specific signal ratios returned by MIMS are equivalent with parallel measurements on a Isotope Ratio Mass Spectrometer, on the basis that the latter returns accurate ratios (see 778000 cal_iso). MIMS and IRMS returned identical values for parallel samples.

Comparison of MIMS to IRMS


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Results

White, A. E., Granger, J., Selden, C., Gradoville, M. R., Potts, L., Bourbonnais, A., Fulweiler, R. W., Knapp, A. N., Mohr, W., Moisander, P. H., Tobias, C. R., Caffin, M., Wilson, S. T., Benavides, M., Bonnet, S., Mulholland, M. R., & Chang, B. X. (2020). A critical review of the 15N2 tracer method to measure diazotrophic production in pelagic ecosystems. Limnology and Oceanography: Methods, 18(4), 129–147. Wiley. https://doi.org/10.1002/lom3.10353