Dataset: Surface water total dissolvable lead concentrations near Station ALOHA from 1997 to 2013

ValidatedFinal no updates expectedDOI: 10.1575/1912/bco-dmo.792783.1Version 1 (2020-02-11)Dataset Type:Cruise Results

Principal Investigator: Edward A. Boyle (Massachusetts Institute of Technology)

BCO-DMO Data Manager: Mathew Biddle (Woods Hole Oceanographic Institution)


Project: Center for Microbial Oceanography: Research and Education (C-MORE)


Abstract

Lead samples from 1997-2013 were collected using the MITESS (Moored In situ Trace Element Serial Sampler) moored sampler (Bell et al., 2002) (1997-2005) and ATE shipboard sampling from HOT occupations (1997-2012), the HOE-DYLAN cruises (2012), and the HOE-PhoR cruises (2013).

Lead samples from 1997-2013 were collected using the MITESS (Moored In situ Trace Element Serial Sampler) moored sampler (Bell et al., 2002) (1997-2005) and ATE shipboard sampling from HOT occupations (1997-2012), the HOE-DYLAN cruises (2012), and the HOE-PhoR cruises (2013). Samples from 1997-2000 were analyzed as described by Boyle et al. (2005) and samples after that by the method described by Lee et al. (2011). The 1997-2013 Pb samples were measured as tdPb, that is analysis of an acidified unfiltered seawater sample. Since dissolved Pb (dPb) in pelagic settings is typically >90% of tdPb (Boyle et al., 2005), the tdPb concentrations from the Station ALOHA time-series are directly comparable to the 2015 KM1513 dPb data, i.e. filtered at 0.4 μm. 


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Results

Hayes, C. T., Fitzsimmons, J. N., Jensen, L. T., Lanning, N. T., Hatta, M., McGee, D., & Boyle, E. A. (2020). A Lagrangian View of Trace Elements and Isotopes in the North Pacific. Journal of Geophysical Research: Oceans, 125(3). doi:10.1029/2019jc015862
Methods

Bell, J., Betts, J., & Boyle, E. (2002). MITESS: a moored in situ trace element serial sampler for deep-sea moorings. Deep Sea Research Part I: Oceanographic Research Papers, 49(11), 2103–2118. doi:10.1016/s0967-0637(02)00126-7
Methods

Boyle, E. A. (2005). Erratum to Edward A. Boyle, Bridget A. Bergquist, Richard A. Kayser and Natalie Mahowald (2005) “Iron, manganese, and lead at Hawaii Ocean Time-series station ALOHA: Temporal variability and an intermediate water hydrothermal plume”, Geochimica et Cosmochimica Acta 69, 933–952. Geochimica et Cosmochimica Acta, 69(21), 5165–5166. doi:10.1016/j.gca.2005.03.006
Methods

Lee, J.-M., Boyle, E. A., Echegoyen-Sanz, Y., Fitzsimmons, J. N., Zhang, R., & Kayser, R. A. (2011). Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 686(1-2), 93–101. doi:10.1016/j.aca.2010.11.052