Dataset: Raw absorbance and R measurements of CRMs

Final no updates expectedDOI: 10.26008/1912/bco-dmo.822399.1Version 1 (2020-08-29)Dataset Type:experimental

Principal Investigator: Ryan Woosley (Massachusetts Institute of Technology)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Improving Accuracy and Precision of Marine Inorganic Carbon Measurements (Inorganic Carbon Meaurements)


Abstract

The temperature dependence of spectrophotometric pH measurements was determined and compared to values calculated from total alkalinity and dissolved inorganic carbon using different combinations of the required dissociation constants. Spectrophotometric measurements were made on two batches of CRMS (179 and 189) between -1.7 and 40 ˚C. This dataset contains the raw absorbance measurements.

Raw absorbance and R measurements of CRMs.


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Related Publications

Results

Woosley, R. J. (2020). Evaluation of the temperature dependence of dissociation constants for the marine carbon system using pH and certified reference materials. Marine Chemistry, 103914. doi:10.1016/j.marchem.2020.103914
Methods

Carter, B. R., Radich, J. A., Doyle, H. L., & Dickson, A. G. (2013). An automated system for spectrophotometric seawater pH measurements. Limnology and Oceanography: Methods, 11(1), 16–27. doi:10.4319/lom.2013.11.16
Methods

Liu, X., Patsavas, M. C., & Byrne, R. H. (2011). Purification and Characterization of meta-Cresol Purple for Spectrophotometric Seawater pH Measurements. Environmental Science & Technology, 45(11), 4862–4868. doi:10.1021/es200665d