Dataset: Carbon isotopes (13C and 14C) and concentrations of dissolved methane (CH4) in surface waters sampled in June 2019 at the Coal Oil Point seep field of the Santa Barbara Basin

ValidatedFinal no updates expectedDOI: 10.26008/1912/bco-dmo.823720.1Version 1 (2020-09-10)Dataset Type:Cruise Results

Principal Investigator: John D. Kessler (University of Rochester)

Contact: DongJoo Joung (University of Rochester)

BCO-DMO Data Manager: Shannon Rauch (Woods Hole Oceanographic Institution)


Project: Constraining Global Coastal Ocean Methane Emissions to the Atmosphere (Coastal Methane Emissions)


Abstract

Carbon isotopes (13C and 14C) and concentrations of dissolved methane (CH4) in surface waters sampled in June 2019 at the Coal Oil Point seep field of the Santa Barbara Basin.

Samples were collected from the small boat R/V Connell, operated by UCSB. Gases dissolved in seawater were extracted following the procedures outlined in Sparrow and Kessler (2017) and Joung et al (2019). As detailed in these prior publications, surface waters (~ 1 m below sea surface) were pumped through a suction hose with a discharge pump and were passed through multiple filters for removing particles. This water was then continuously passed through a gas-permeable membrane to vacuum extract the dissolved gases in the seawater.

Following these at-sea sample collection procedures, the extracted gas samples were purified and analyzed following vacuum line procedures previously detailed in Sparrow and Kessler (2017).

Please see the Sparrow and Kessler (2017) for detailed descriptions and validation tests for these procedures.

Dissolved methane concentration measurements were conducted using a headspace equilibration technique previously described in Weinstein et al. (2016) and Leonte et al (2017).


Related Datasets

IsRelatedTo

Dataset: Radiocarbon in methane at ocean margins
Kessler, J. D., Joung, D. (2021) Radiocarbon in methane from waters of the US Atlantic and Pacific margins as collected on R/V Hugh Sharp cruise HRS1713 and R/V Rachel Carson cruise RC0026 in 2017 and 2019. Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2021-09-27 doi:10.26008/1912/bco-dmo.861576.1

Related Publications

General

Sparrow, K. J., Kessler, J. D., Southon, J. R., Garcia-Tigreros, F., Schreiner, K. M., Ruppel, C. D., Miller, J. B., Lehman, S. J., & Xu, X. (2018). Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf. Science Advances, 4(1), eaao4842. https://doi.org/10.1126/sciadv.aao4842
Methods

Joung, D., Leonte, M., & Kessler, J. D. (2019). Methane Sources in the Waters of Lake Michigan and Lake Superior as Revealed by Natural Radiocarbon Measurements. Geophysical Research Letters, 46(10), 5436–5444. doi:10.1029/2019gl082531
Methods

Leonte, M., Kessler, J. D., Kellermann, M. Y., Arrington, E. C., Valentine, D. L., & Sylva, S. P. (2017). Rapid rates of aerobic methane oxidation at the feather edge of gas hydrate stability in the waters of Hudson Canyon, US Atlantic Margin. Geochimica et Cosmochimica Acta, 204, 375–387. doi:10.1016/j.gca.2017.01.009
Methods

Sparrow, K. J., & Kessler, J. D. (2017). Efficient collection and preparation of methane from low concentration waters for natural abundance radiocarbon analysis. Limnology and Oceanography: Methods, 15(7), 601–617. doi:10.1002/lom3.10184
Methods

Weinstein, A., Navarrete, L., Ruppel, C., Weber, T. C., Leonte, M., Kellermann, M. Y., Arrington, E. C., Valentine, D. L., Scranton, M. I., & Kessler, J. D. (2016). Determining the flux of methane into Hudson Canyon at the edge of methane clathrate hydrate stability. Geochemistry, Geophysics, Geosystems, 17(10), 3882–3892. https://doi.org/10.1002/2016gc006421