Table of Contents

• Coverage
• Dataset Description
  • Data Processing Description
• Data Files
• Supplemental Files
• Related Publications
• Related Datasets
• Parameters
• Instruments
• Deployments
• Project Information
• Program Information
• Funding

Bottle data collected by the GTC (GEOTRACES Trace element Carousel) and ODF (Ocean Data Facility) CTD rosettes, underway, and tow fish on Leg 2 of the US GEOTRACES Pacific Meridional Transect (PMT) cruise (GP15) from October to November 2018. Data from the different sampling systems was compiled into one file by ODF. For complete acquisition and processing information, refer to the cruise report (PDF).

Unit conversion for nutrients and oxygen:
Nutrients and oxygen were measured onboard the ship in umol/L, but are reported in umol/kg in this dataset. The ODF group used the following protocols for conversion:

For converting nutrient and oxygen measurements to units of umol/kg, density was calculated according to EOS-80, using the best available salinities (either bottle or CTD, depending on quality flag in that order). The source for temperature depends on the analyte. For oxygen, the draw temperature at the time of collection was used for density calculations (Culberson, 1991; WHP Operations and Methods, Dissolved Oxygen). For nutrients, the measured analytical lab temperature was used for density calculations (Becker et al., 2021; GO-SHIP Repeat Hydrography Manual: The precise and accurate determination of dissolved inorganic nutrients in seawater, using Continuous Flow Analysis methods). The lab temperature was measured at the location of the instrument, and the samples themselves were allowed to come to lab temperature before analysis.

Quality Flags:
FLAG columns follow the WOCE Hydrographic Program (WHP) quality flag definitions.

The WHP quality codes for the water bottle itself are:
1 = Bottle information unavailable.
2 = No problems noted.
3 = Leaking.
4 = Did not trip correctly.
5 = Not reported.
6 = Significant discrepancy in measured values between Gerard and Niskin bottles.
7 = Unknown problem.
8 = Pair did not trip correctly. Note that the Niskin bottle can trip at an unplanned depth while the Gerard trips correctly and vice versa.
9 = Samples not drawn from this bottle.
(Flags 6, 7, and 8 apply primarily to large volume samplers.)

The WHP bottle parameter data quality codes are:
1 = Sample for this measurement was drawn from water bottle but analysis not received. Note that if water is drawn for any measurement from a water bottle, the quality flag for that parameter must be set equal to 1 initially to ensure that all water samples are accounted for.
2 = Acceptable measurement.
3 = Questionable measurement.
4 = Bad measurement.
5 = Not reported.
6 = Mean of replicate measurements (Number of replicates should be specified).
7 = Manual chromatographic peak measurement.
8 = Irregular digital chromatographic peak integration.
9 = Sample not drawn for this measurement from this bottle.

The WHP CTD data quality codes are:
1 = Not calibrated.
2 = Acceptable measurement.
3 = Questionable measurement.
4 = Bad measurement.
5 = Not reported.
6 = Interpolated over >2 dbar interval.
7 = Despiked.
8 = Not assigned for CTD data.
9 = Not sampled.

BCO-DMO Processing:
- changed time format to hhmm;
- added ISO8601 date/time column;
- filled in missing values with "nd";
- replaced -999 and -999.000 with "nd";
- Version history:
  - 2021-05-05 (v5; current) - replaced with file received 2021-05-03, which includes several corrections/edits.
  - 2020-09-22 (v4) - from original file named "33RR20180918_hy1_v5_door_barcodes.xlsx"; contains GEOTRACES DOoR-formatted names; splits the data into one file per leg.
  - 2020-03-02 (v3) - from original file named "33RR20180918_hy1_v5.xlsx" submitted on 02-March-2020.
  - 2019-10-22 (v2) - from original file named "33RR20180918_hy1_v4_pjl.xlsx" submitted on 2019-10-14.
  - 2019-09-25 (v1) - from original file named "33RR20180918_hy1_v3.csv" submitted on 2019-09-10.

A 60-day research cruise took place in 2018 along a transect form Alaska to Tahiti at 152° W. A description of the project titled "Collaborative Research: Management and implementation of the US GEOTRACES Pacific Meridional Transect", funded by NSF, is below. Further project information is available on the US GEOTRACES website and on the cruise blog. A detailed cruise report is also available as a PDF.

Description from NSF award abstract:
GEOTRACES is a global effort in the field of Chemical Oceanography in which the United States plays a major role. The goal of the GEOTRACES program is to understand the distributions of many elements and their isotopes in the ocean. Until quite recently, these elements could not be measured at a global scale. Understanding the distributions of these elements and isotopes will increase the understanding of processes that shape their distributions and also the processes that depend on these elements. For example, many "trace elements" (elements that are present in very low amounts) are also important for life, and their presence or absence can play a vital role in the population of marine ecosystems. This project will launch the next major U.S. GEOTRACES expedition in the Pacific Ocean between Alaska and Tahiti. The award made here would support all of the major infrastructure for this expedition, including the research vessel, the sampling equipment, and some of the core oceanographic measurements. This project will also support the personnel needed to lead the expedition and collect the samples.

This project would support the essential sampling operations and infrastructure for the U.S. GEOTRACES Pacific Meridional Transect along 152° W to support a large variety of individual science projects on trace element and isotope (TEI) biogeochemistry that will follow. Thus, the major objectives of this management proposal are: (1) plan and coordinate a 60 day research cruise in 2018; (2) obtain representative samples for a wide variety of TEIs using a conventional CTD/rosette, GEOTRACES Trace Element Sampling Systems, and in situ pumps; (3) acquire conventional CTD hydrographic data along with discrete samples for salinity, dissolved oxygen, algal pigments, and dissolved nutrients at micro- and nanomolar levels; (4) ensure that proper QA/QC protocols are followed and reported, as well as fulfilling all GEOTRACES intercalibration protocols; (5) prepare and deliver all hydrographic data to the GEOTRACES Data Assembly Centre (via the US BCO-DMO data center); and (6) coordinate all cruise communications between investigators, including preparation of a hydrographic report/publication. This project would also provide baseline measurements of TEIs in the Clarion-Clipperton fracture zone (~7.5°N-17°N, ~155°W-115°W) where large-scale deep sea mining is planned. Environmental impact assessments are underway in partnership with the mining industry, but the effect of mining activities on TEIs in the water column is one that could be uniquely assessed by the GEOTRACES community. In support of efforts to communicate the science to a wide audience the investigators will recruit an early career freelance science journalist with interests in marine science and oceanography to participate on the cruise and do public outreach, photography and/or videography, and social media from the ship, as well as to submit articles about the research to national media. The project would also support several graduate students.

GEOTRACES is a SCOR sponsored program; and funding for program infrastructure development is provided by the U.S. National Science Foundation.

GEOTRACES gained momentum following a special symposium, S02: Biogeochemical cycling of trace elements and isotopes in the ocean and applications to constrain contemporary marine processes (GEOSECS II), at a 2003 Goldschmidt meeting convened in Japan. The GEOSECS II acronym referred to the Geochemical Ocean Section Studies To determine full water column distributions of selected trace elements and isotopes, including their concentration, chemical speciation, and physical form, along a sufficient number of sections in each ocean basin to establish the principal relationships between these distributions and with more traditional hydrographic parameters;

* To evaluate the sources, sinks, and internal cycling of these species and thereby characterize more completely the physical, chemical and biological processes regulating their distributions, and the sensitivity of these processes to global change; and

* To understand the processes that control the concentrations of geochemical species used for proxies of the past environment, both in the water column and in the substrates that reflect the water column.

GEOTRACES will be global in scope, consisting of ocean sections complemented by regional process studies. Sections and process studies will combine fieldwork, laboratory experiments and modelling. Beyond realizing the scientific objectives identified above, a natural outcome of this work will be to build a community of marine scientists who understand the processes regulating trace element cycles sufficiently well to exploit this knowledge reliably in future interdisciplinary studies.

Expand "Projects" below for information about and data resulting from individual US GEOTRACES research projects.