Dataset: Nutrients, nitrate isotopes, and DON isotopes data from samples collected in the Gulf of Mexico on R/V Nancy Foster cruises NF1704 and NF1802 in May 2017 and May 2018

ValidatedFinal no updates expectedDOI: 10.26008/1912/bco-dmo.834984.1Version 1 (2020-12-31)Dataset Type:Cruise Results

Principal Investigator: Angela N. Knapp (Florida State University EOAS)

Co-Principal Investigator: Michael R. Landry (University of California-San Diego Scripps)

BCO-DMO Data Manager: Dana Stuart Gerlach (Woods Hole Oceanographic Institution)


Program: Second International Indian Ocean Expedition (IIOE-2)

Project: Collaborative Research: Mesoscale variability in nitrogen sources and food-web dynamics supporting larval southern bluefin tuna in the eastern Indian Ocean (BLOOFINZ-IO)


Abstract

This data set includes water column inorganic nutrient and dissolved organic nitrogen (DON) concentration and nitrate+nitrite d15N and d18O and DON δ15N measurements from May 2017 and May 2018 cruises in the North/Central Gulf of Mexico that were used together with sinking particulate N data to construct δ15N budgets.

Water column samples were collected by Niskin bottle on a CTD rosette (“CTD profile”) in the North/Central Gulf of Mexico during Nancy Foster cruises (NF17-04, NF18-02) in May 2017 and May 2018, as part of the NOAA RESTORE (aka BLOOFINZ-GoM) project.  All samples were 0.2 µm filtered into pre-washed HDPE bottles which were frozen at -20 degrees Celsius until analysis on land. 

Acquisition and associated instruments:
Nitrate+nitrite concentration was measured on a Thermo 42i NOx analyzer
Nitrate+nitrite d15N was measured using a Thermo Finnigan Delta V isotope ratio mass spectrometer.
Phosphate concentration was determined using a Shimadzu UV-1800 uv-vis spectrophotometer.
Ammonium concentration was determined using a Turner Trilogy fluorometer.


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Methods

Braman, R. S., & Hendrix, S. A. (1989). Nanogram nitrite and nitrate determination in environmental and biological materials by vanadium(III) reduction with chemiluminescence detection. Analytical Chemistry, 61(24), 2715–2718. doi:10.1021/ac00199a007
Methods

Casciotti, K. L., Sigman, D. M., Hastings, M. G., Böhlke, J. K., & Hilkert, A. (2002). Measurement of the Oxygen Isotopic Composition of Nitrate in Seawater and Freshwater Using the Denitrifier Method. Analytical Chemistry, 74(19), 4905–4912. doi:10.1021/ac020113w
Methods

Holmes, R. M., Aminot, A., Kérouel, R., Hooker, B. A., & Peterson, B. J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Canadian Journal of Fisheries and Aquatic Sciences, 56(10), 1801–1808. doi:10.1139/f99-128
Methods

Knapp, A. N., Sigman, D. M., & Lipschultz, F. (2005). N isotopic composition of dissolved organic nitrogen and nitrate at the Bermuda Atlantic Time-series Study site. Global Biogeochemical Cycles, 19(1). doi:10.1029/2004gb002320
Methods

Koroleff, F. (1968). Determination of total phosphorus in natural waters by means of persulfate oxidation.