Dataset: Total Mercury Concentrations Collected from Scripps Pier in La Jolla, CA from December 2020 to December 2024

ValidatedFinal no updates expectedDOI: 10.26008/1912/bco-dmo.950021.1Version 1 (2025-02-04)Dataset Type:Other Field Results

Principal Investigator: Amina T. Schartup (University of California-San Diego Scripps)

Co-Principal Investigator: Carl Lamborg (University of California-Santa Cruz)

Student, Contact: Hannah M. Adams (University of California-San Diego Scripps)

BCO-DMO Data Manager: Karen Soenen (Woods Hole Oceanographic Institution)


Project: Collaborative Proposal: Unravelling the Oceanic Dimethylmercury Cycle (DMHg in the Ocean)


Abstract

weekly collected samples of Total Mercury from Scripps Pier in La Jolla, CA from December 2020 to December 2024 to capture variability over multiple years. Samples were collected using a peristaltic pump equipped with weighted sample tubing into pre-cleaned glass bottles. Samples were analyzed via a Tekran 2600 Automatic Mercury Sampler.

Weekly sampling was conducted between December 2020 and November 2024 at the Ellen Browning Scripps Memorial Pier (Scripps Pier) in La Jolla, CA (32.8634 °N, 117.2546 °W). Total Hg (THg) and total methylated Hg (MeHg; not shown) were sampled at depths of < 0.5 m and 6 m using a peristaltic pump equipped with weighted sample tubing. Seawater was pumped into clean borosilicate glass bottles (I-Chem) and returned to the lab. MeHg and THg samples were acidified with 0.4% hydrochloric acid (HCl; Trace Metal Grade, J.T. Baker), and stored at 4°C until analysis within 6 months.


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Methods

Lamborg, C. H., Hammerschmidt, C. R., Gill, G. A., Mason, R. P., & Gichuki, S. (2012). An intercomparison of procedures for the determination of total mercury in seawater and recommendations regarding mercury speciation during GEOTRACES cruises. Limnology and Oceanography: Methods, 10(2), 90–100. doi:10.4319/lom.2012.10.90
Methods

U.S. Environmental Protection Agency. Method 1631, Revision E: Mercury in Water by Oxidation, Purge and Trap, and Cold Vapor Atomic Fluorescence Spectrometry Method 1631, Revision E: Washington, D.C., 2002.
Methods

Yang, L., Willie, S., & Sturgeon, R. E. (2005). Ultra-trace determination of mercury in water by cold-vapor generation isotope dilution mass spectrometry. Journal of Analytical Atomic Spectrometry, 20(11), 1226. https://doi.org/10.1039/b506695f